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https://hdl.handle.net/2440/115794
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Type: | Journal article |
Title: | Enhanced photo-Fenton-like process over Z-scheme CoFe₂O₄/g-C₃N₄ Heterostructures under natural indoor light |
Other Titles: | Enhanced photo-Fenton-like process over Z-scheme CoFe(2)O(4)/g-C(3)N(4) Heterostructures under natural indoor light |
Author: | Yao, Y. Wu, G. Lu, F. Wang, S. Hu, Y. Zhang, J. Huang, W. Wei, F. |
Citation: | Environmental Science and Pollution Research, 2016; 23(21):21833-21845 |
Publisher: | Springer-Verlag |
Issue Date: | 2016 |
ISSN: | 0944-1344 1614-7499 |
Statement of Responsibility: | Yunjin Yao, Guodong Wu, Fang Lu, Shaobin Wang, Yi Hu, Jie Zhang, Wanzheng Huang, Fengyu Wei |
Abstract: | Low-cost catalysts with high activity and stability toward producing strongly oxidative species are extremely desirable, but their development still remains a big challenge. Here, we report a novel strategy for the synthesis of a magnetic CoFe2O4/C3N4 hybrid via a simple self-assembly method. The CoFe2O4/C3N4 was utilized as a photo-Fenton-like catalyst for degradation of organic dyes in the presence of H2O2 under natural indoor light irradiation, a green and energy-saving approach for environmental cleaning. It was found the CoFe2O4/C3N4 hybrid with a CoFe2O4: g-C3N4 mass ratio of 2:1 can completely degrade Rhodamine B nearly 100 % within 210 min under room-light irradiation. The effects of the amount of H2O2 (0.01-0.5 M), initial dye concentration (5-20 mg/L), solution pH (3.08-10.09), fulvic acid concentration (5-50 mg/L), different dyes and catalyst stability on the organic dye degradation were investigated. The introduction of CoFe2O4 on g-C3N4 produced an enhanced separation efficiency of photogenerated electron - hole pairs by a Z-scheme mechanism between the interfaces of g-C3N4 and CoFe2O4, leading to an excellent activity as compared with either g-C3N4 or CoFe2O4 and their mixture. This study demonstrates an efficient way to construct the low-cost magnetic CoFe2O4/C3N4 heterojunction as a typical Z-scheme system in environmental remediation. |
Keywords: | CoFe₂O₄; G-C₃N₄; photo-Fenton-like; organic pollutants; photocatalysis; Rhodamine B |
Description: | Published online: 14 August 2016 |
Rights: | © Springer-Verlag Berlin Heidelberg 2016 |
DOI: | 10.1007/s11356-016-7329-2 |
Grant ID: | http://purl.org/au-research/grants/arc/DP150103026 |
Published version: | http://dx.doi.org/10.1007/s11356-016-7329-2 |
Appears in Collections: | Aurora harvest 8 Chemical Engineering publications |
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