Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/17792
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Construction of carbon chains on ruthenium and osmium carbonyl clusters |
Author: | Bruce, M. Humphrey, P. Melino, G. Skelton, B. White, A. Zaitseva, N. |
Citation: | Inorganica Chimica Acta, 2005; 358(5):1453-1468 |
Publisher: | Elsevier Science SA |
Issue Date: | 2005 |
ISSN: | 0020-1693 1873-3255 |
Statement of Responsibility: | Michael I. Bruce, Paul A. Humphrey, Giovanni Melino, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
Abstract: | We have used the elimination of AuX(PR3) (X = halide, R = Ph, tol) that occurs in reactions of alkynylgold(I)–phosphine complexes with M3(μ-H)3 (μ3-CBr) (CO)9 (M = Ru, Os) to prepare the complexes M3(μ-H)3(μ3-CCtriple bond; length of mdashCR)(CO)9 [M = Ru, R = Ph 2, Ctriple bond; length of mdashCSiMe3 3, Fc 4, Ctriple bond; length of mdashCFc 6-Ru, Ctriple bond; length of mdashC[Ru(PPh3)2Cp] 8; M = Os, R = Ctriple bond; length of mdashCFc 6-Os, Ctriple bond; length of mdashCCtriple bond; length of mdashCFc 7], Fc′{(μ3-Ctriple bond; length of mdashCC)Ru3(μ-H)3(CO)9}25, and bis-cluster-capped carbon chain complexes {M3(μ-H)3(CO)9}2{μ3:μ3-C(Ctriple bond; length of mdashC)nC} (M = Ru, n = 2 9, 3 10-Ru; M = Os, n = 3 10-Os) and {(L)(OC)8(μ-H)3M3}C(Ctriple bond; length of mdashC)nC{Co3(μ-dppm)(CO)7} (n = 1, M = Ru, L = CO 11, PPh3 12-Ru/P; n = 2, L = CO 12-Ru, PPh3 13; M = Os, L = CO 12-Os) in good to excellent yields. X-ray structural determinations of 2–5, 6-Ru, 6-Os, 7, 9, 11, 12-Ru, 12-Os and 12-Ru/P are reported. |
Description: | Copyright © 2004 Elsevier B.V. All rights reserved. |
DOI: | 10.1016/j.ica.2004.08.027 |
Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504086/description#description |
Published version: | http://dx.doi.org/10.1016/j.ica.2004.08.027 |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.