Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/34925
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Coordination chemistry of di-2-pyridylmethane and related bridging ligands with silver(i), copper(ii), palladium(ii) and zinc(ii) |
Author: | Steel, P. Sumby, C. |
Citation: | Dalton Transactions: an international journal of inorganic chemistry, 2003; 23(23):4505-4515 |
Publisher: | Royal Soc Chemistry |
Issue Date: | 2003 |
ISSN: | 1477-9226 1477-9234 |
Statement of Responsibility: | Peter J. Steel and Christopher J. Sumby |
Abstract: | Di-2-pyridylmethane ( 1) and the bridging ligands 1,1,2,2-tetra(2-pyridyl)ethane ( 2), 1,1,2,2-tetra(2-pyridyl)ethan-2-ol ( 3) and tetra(2-pyridyl)ethene ( 4) chelate to metal atoms with the formation of 6-membered chelate rings. The utility of these ligands in coordination chemistry and as metallosupramolecular synthons was probed by reaction with silver, copper, palladium and zinc salts. On reaction with AgNO3 the model ligand, 1, formed a 1-D coordination polymer with an unusual bridging mode and with Cu(NO3)2 underwent oxidation to produce a Cu6(L)4(L = 5, di-2-pyridylmethanediol) complex. The bridging ligands 2 and 4 formed several discrete dinuclear complexes, a [2 + 2]-dimetallomacrocycle and a 1-D coordination polymer. Ligand 3 was demonstrated to be less stable and underwent three different solvolysis reactions to give a range of products that were characterised by X-ray crystallography. |
Description: | © Royal Society of Chemistry 2003 |
DOI: | 10.1039/b309479k |
Published version: | http://dx.doi.org/10.1039/b309479k |
Appears in Collections: | Aurora harvest 6 Chemistry publications Environment Institute publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.