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https://hdl.handle.net/2440/4339
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Type: | Journal article |
Title: | Preparation and structure of Ru2(m-O2CCF3)2(CO)4(NCMe)2 |
Author: | Bruce, M. Zaitseva, N. Skelton, B. White, A. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 1999; 52(6):621-623 |
Publisher: | CSIRO Publishing |
Issue Date: | 1999 |
ISSN: | 0004-9425 |
Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, Natasha N. Zaitseva and Allan H. White |
Abstract: | The molecular structure of Ru2(µ-O2CCF3)2(CO)4(NCMe)2, obtained from Ru3(CO)10(NCMe)2 and CF3CO2H, or from Ru3(CO)12 and CF3CO2H in a CH2Cl2/MeCN mixture, is presented. The central Ru–Ru bond [2·683(1) Å] is bridged by the two carboxylato ligands [Ru–O (average) 2·133 Å]. Each ruthenium carries mutually cis CO ligands approximately trans to the Ru–O vectors and an MeCN ligand in the axial position [Ru–N (average) 2·18 Å]. |
DOI: | 10.1071/CH99005 |
Published version: | http://www.publish.csiro.au/nid/51/paper/CH99005.htm |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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