Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/4435
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Tuning aurophilic interactions in dinuclear phosphinegold(I) thiolates containing hydrogen bonding functionalities |
Author: | Smyth, Douglas Robert Hester, James Young, Victor G. Tiekink, Edward Richard Tom |
Citation: | CrystEngComm, 2002; 4(86):517-521 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2002 |
ISSN: | 1466-8033 |
School/Discipline: | School of Chemistry and Physics School of Chemistry and Physics : Chemistry |
Statement of Responsibility: | Douglas R. Smyth, James Hester, Victor G. Young, Jr and Edward R.T. Tiekink |
Abstract: | A common feature of the solid state structures of [(AuSC₆H₄{C(=O)Y}-2)₂(µ-dppf)], where dppf is bis(diphenylphosphine)ferrocene, and Y = OH (1), NH₂(2) and N(H)Me (3) is the formation of a chain motif. Association between the molecules is found to be highly dependent on the nature of Y so that in 1 only hydrogen bonding between molecules is observed. In 2, both hydrogen bonding and aurophilic interactions are found. By contrast, in 3 only aurophilic interactions contribute to the formation of the chain. These results are consistent with a similar energy of stabilisation and structure-directing propensity for the hydrogen bonding and aurophilic association operating in these systems. |
Rights: | © The Royal Society of Chemistry 2002 |
DOI: | 10.1039/b207045f |
Appears in Collections: | Chemistry publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.