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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/4608
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dc.contributor.authorBruce, M.-
dc.contributor.authorHall, B.-
dc.contributor.authorZaitseva, N.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.date.issued1996-
dc.identifier.citationJournal of Organometallic Chemistry, 1996; 522(2):307-310-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/2440/4608-
dc.description.abstractReactions of RuCl(PPh3)2Cp* with 1-alkynes in non-polar solvents afford the neutral vinylidene complexes RuCl(C=CHR)(PPh3) Cp* [R=Ph (X-ray structure), Bu1, SiMe3, CO2Me]; a novel 1,3 elimination of HCl induced by NaOMe in the presence of a variety of ligands gives the chiral-at-metal complexes Ru(Ctriple bond; length as m-dashCR)(L)(PPh3)Cp* [L=CO, C2H4 (X-ray structure), PR3, P(OR)3, O2, S2, CS2 (for example)].-
dc.description.statementofresponsibilityMichael I. Bruce, Ben C. Hall, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White-
dc.description.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description-
dc.language.isoen-
dc.publisherElsevier BV-
dc.rightsCopyright © 1996 Published by Elsevier Science B.V.-
dc.source.urihttp://dx.doi.org/10.1016/0022-328x(96)06200-6-
dc.subjectCrystal structure-
dc.subjectChirality-
dc.subjectRuthenium-
dc.subjectVinylidene-
dc.titleSome neutral ruthenium complexes and a novel 1,3-elimination reaction reaction: Preparation of some chiral ruthenium acetylides-
dc.typeJournal article-
dc.identifier.doi10.1016/0022-328X(96)06200-6-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest 6
Chemistry publications

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