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https://hdl.handle.net/2440/4669
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DC Field | Value | Language |
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dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.contributor.author | Zaitseva, N. | - |
dc.date.issued | 2001 | - |
dc.identifier.citation | Dalton Transactions: an international journal of inorganic chemistry, 2001; (24):3627-3633 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.issn | 0300-9246 | - |
dc.identifier.uri | http://hdl.handle.net/2440/4669 | - |
dc.description.abstract | Thermolysis of Ru{η³-C(CN)₂CPhC=C(CN)₂}(PPh₃)Cp* (2), obtained from Ru(C≡CPh)(PPh₃)₂Cp* and tetracyanoethene, has given the three complexes Ru{η¹,η²(C,N)-C(CN)=C(CN)CPh=C(CN)(C=N)}(PPh₃)Cp* (3), {Ru(PPh₃)Cp*}{μ-N:η³-NCC(CN)=CPhC=C(CN)₂}{μ-η¹:N-C(CN)=C(CN)CPh=C(CN)₂}{RuCp*} (4) and {Ru[η³-C(CN)₂=CPhC=C(CN)₂]Cp*}₃ (5). All four complexes have been characterised by single-crystal X-ray structure determinations and contain isomeric forms of the C₄(CN)₄Ph ligand. Unusual features of the molecular structures are (i) the presence of a side-on (η²) CN group in 3; (ii) formation of a second isomer of the polycyanocarbon ligand by CN migration to an adjacent carbon, in 3 and 4; (iii) the use of one or more CN groups to bridge ruthenium centres in 4 and 5; and (iv) the complete loss of PPh₃ ligands during the formation of the trimer 5. Although there are three crystallographically distinct RuCp* groups in 5, only one Cp* resonance is found in solution NMR spectra, suggesting that oligomer formation by facile CN–Ru bond breaking and making is occurring. | - |
dc.description.statementofresponsibility | Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva | - |
dc.language.iso | en | - |
dc.publisher | Royal Soc Chemistry | - |
dc.rights | © Royal Society of Chemistry 2001 | - |
dc.source.uri | http://www.rsc.org/publishing/journals/DT/article.asp?doi=b105131h | - |
dc.title | Reactions of Ru(C≡CPh)(PPh₃)₂Cp* with tetracyanoethene: cycloaddition, formation of unusual ŋ²-CNR complexes and oligomerisation via bridging cyanocarbon ligands | - |
dc.title.alternative | Reactions of Ru(Ctriple barCPh)(PPh(3))(2)Cp* with tetracyanoethene: cycloaddition, formation of unusual n(2)-CNR complexes and oligomerisation via bridging cyanocarbon ligands | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/b105131h | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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