Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4673
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| Type: | Journal article |
| Title: | A new "Sn₁₂" oxo-cluster-how to flatten the football |
| Other Titles: | A new "Sn(12)" oxo-cluster-how to flatten the football |
| Author: | Zobel, Bernhard Costin, J. Vincent, Beverly R. Tiekink, Edward Richard Tom Dakternieks, Dainis |
| Citation: | Journal of the Chemical Society, Dalton Transactions, 2000; 22:4021-4022 |
| Publisher: | Royal Society of Chemistry |
| Issue Date: | 2000 |
| ISSN: | 0300-9246 |
| School/Discipline: | School of Chemistry and Physics |
| Abstract: | Controlled hydrolysis of [(ClCH₂CO₂)₃Sn(CH₂)₃Sn(O₂CCH₂Cl) ₃]n 1 resulted in the hitherto unknown “Sn₁₂” cluster {[Sn(CH₂)₃Sn] ₆ (ClCH₂CO₂)₁₄ (OH) ₂O₁₀} 3 with trimethylene “handles”: compound 3 has all twelve tin atoms nearly coplanar, in stark contrast to previously described “Sn₁₂” clusters which have a spherical football structure. |
| Description: | © The Royal Society of Chemistry 2000 |
| DOI: | 10.1039/b007896o |
| Appears in Collections: | Chemistry publications |
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