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https://hdl.handle.net/2440/51871
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Type: | Journal article |
Title: | Bis[(μ-iodo)iodo-η-cyclopentadienylruthenium(III)], 'CpRuI₂' = [CpRuI₂]₂: a further example of a [CpXM(μ-X)₂MXCp] parent with cis arrangement |
Other Titles: | Bis[(mu-iodo)iodo-eta-cyclopentadienylruthenium(III)], 'CpRuI(2)' = [CpRuI(2)](2): a further example of a [CpXM(mu-X)(2)MXCp] parent with cis arrangement |
Author: | Bruce, M. Jevric, M. Skelton, B. White, A. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2008; 634(6-7):1093-1096 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2008 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Martyn Jevric, Brian W. Skelton, and Allan H. White |
Abstract: | <jats:title>Abstract</jats:title><jats:p>The very limited array of (structurally described) adducts of the form [CpMX<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub> ≡ [CpMX(μ‐X)<jats:sub>2</jats:sub>MXCp] with the unsubstituted/parent Cp (≡ C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>, cyclopentadienyl) ligand is augmented by a study of [CpIRu(μ‐I)<jats:sub>2</jats:sub>RuICp], found to be isotypic with the recently described chloride and, with it, providing the only examples of such dimers in their ‘<jats:italic>cis</jats:italic>’ form, <jats:italic>i.e</jats:italic>., the terminal‐X and Cp pairs to the same side of the Ru<jats:sub>2</jats:sub>(μ‐X)<jats:sub>2</jats:sub> arrays, which are appreciably folded at the X···X lines, with the short Ru···Ru distances (2.7748(6) (X = Cl), 2.9034(8) Å (X = I)), consistent with the presence of appreciable metal‐metal bonding (<jats:italic>cf.</jats:italic> the M = Cr, X = Cl counterpart which is <jats:italic>trans</jats:italic>, Cr···Cr 3.3447(8) Å).</jats:p> |
Keywords: | Ruthenium Halides Iodine Binuclear complexes Metal-metal bond Crystal structure |
DOI: | 10.1002/zaac.200800019 |
Published version: | http://dx.doi.org/10.1002/zaac.200800019 |
Appears in Collections: | Aurora harvest 5 Chemistry publications |
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