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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/60047
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dc.contributor.authorBruce, M.-
dc.contributor.authorZaitseva, N.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.date.issued2010-
dc.identifier.citationZeitschrift fuer Anorganische und Allgemeine Chemie, 2010; 636(6):1075-1077-
dc.identifier.issn0044-2313-
dc.identifier.issn1521-3749-
dc.identifier.urihttp://hdl.handle.net/2440/60047-
dc.description.abstractThe reaction between Ru(C≡CH)(dppe)Cp* and Co3(μ3-CBr)(CO)9 in the presence of Pd(PPh3)4/CuI afforded dark red Co3{μ3-CC(O)C≡C[Ru(dppe)Cp*]}(CO)8(PPh3), whose formation may involve attack of the Ru-ethynyl fragment on an intermediate clusterbound CCO ligand; abstraction of PPh3 from the palladium catalyst also occurs.-
dc.description.statementofresponsibilityMichael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White-
dc.language.isoen-
dc.publisherWiley-V C H Verlag GMBH-
dc.rightsCopyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.source.urihttp://dx.doi.org/10.1002/zaac.200900535-
dc.subjectCobalt-
dc.subjectRuthenium-
dc.subjectCluster compounds-
dc.subjectCrystal structure-
dc.subjectAcyl-ethynyl complex-
dc.titleFormation of an acyl-ethynyl-methylidyne complex of cobalt: structure of Co₃{μ₃-CC(O)C≡C [Ru(dppe)Cp*]} (CO)₈(PPh₃)-
dc.title.alternativeFormation of an acyl-ethynyl-methylidyne complex of cobalt: structure of Co(3){mu(3)-CC(O)Ctriple barC [Ru(dppe)Cp*]} (CO)(8)(PPh(3))-
dc.typeJournal article-
dc.identifier.doi10.1002/zaac.200900535-
dc.relation.grantARC-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
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Chemistry publications

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