Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/66042
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Isoreticular Metalation of Metal-Organic Frameworks |
Author: | Doonan, C. Morris, W. Furukawa, H. Yaghi, O. |
Citation: | Journal of the American Chemical Society, 2009; 131(27):9492-9493 |
Publisher: | Amer Chemical Soc |
Issue Date: | 2009 |
ISSN: | 0002-7863 1520-5126 |
Statement of Responsibility: | Christian J. Doonan, William Morris, Hiroyasu Furukawa, and Omar M. Yaghi |
Abstract: | Sequential covalent transformation and metalation were performed on (Zn(4)O)(3)(BDC-NH(2))(3)(BTB)(4) with maintenance of crystallinity and porosity. Reaction of (Zn(4)O)(3)(BDC-NH(2))(3)(BTB)(4) with 2-pyridinecarboxaldehyde in toluene at room temperature for 5 days resulted in the formation of the extended crystalline structure (Zn(4)O)(3)(BDC-C(6)H(5)N(2))(3)(BTB)(4), which possesses iminopyridine moieties covalently bound to the organic links of the framework. Subsequent reaction with PdCl(2)(CH(3)CN)(2) in CH(2)Cl(2) at room temperature for 12 h yielded the metalated metal-organic framework (Zn(4)O)(3)(BDC-C(6)H(5)N(2)PdCl(2))(3)(BTB)(4). Both functionalized materials retained high crystallinity and were permanently porous with high surface areas [3200 and 1700 m(2) g(-1) for (Zn(4)O)(3)(BDC-C(6)H(5)N(2))(3)(BTB)(4) and (Zn(4)O)(3)(BDC-C(6)H(5)N(2)PdCl(2))(3)(BTB)(4), respectively.]. |
Rights: | © 2009 American Chemical Society |
DOI: | 10.1021/ja903251e |
Published version: | http://dx.doi.org/10.1021/ja903251e |
Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.