Adelaide Research & Scholarship
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https://hdl.handle.net/2440/74361
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| Type: | Journal article |
| Title: | Synthesis of a liphagal-frondosin c hybrid and speculation on the biosynthesis of the frondosins |
| Author: | Pepper, H. Kuan, K. George, J. |
| Citation: | Organic Letters, 2012; 14(6):1524-1527 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2012 |
| ISSN: | 1523-7060 1523-7052 |
| Statement of Responsibility: | Henry P. Pepper, Kevin K. W. Kuan, and Jonathan H. George |
| Abstract: | A hypothesis for the biosynthesis of the frondosins A-E is presented. Synthesis of a liphagal-frondosin C hybrid molecule has been achieved, with the frondosin C 6-7-5-6 ring system being constructed by a photochemical process that follows an intramolecular Paternò-Büchi reaction/fragmentation pathway. |
| Keywords: | Animals Porifera Marine Biology Molecular Structure Cyclization Catalysis Heterocyclic Compounds, 4 or More Rings |
| Rights: | © 2012 American Chemical Society |
| DOI: | 10.1021/ol300257v |
| Published version: | http://dx.doi.org/10.1021/ol300257v |
| Appears in Collections: | Aurora harvest Chemistry publications |
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